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Mass and heat balance calculations and economic evaluation of an innovative biomass pyrolysis project

Quanyuan WEI, Yongshui QU, Tianwei TAN

《化学科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 355-361 doi: 10.1007/s11705-010-0567-9

摘要： Biomass can be converted into flammable gas, charcoal, wood vinegar, wood tar oil and noncombustible materials with thermo-chemical pyrolysis reactions. Many factors influence these processes, such as the properties of the raw materials, and temperature control and these will affect the products that are produced. Based on the data from a straw pyrolysis demonstration project, the mass and heat balance of the biomass pyrolysis process were analyzed. The statistical product and service solutions (SPSS) statistical method was used to analyze the data which were monitored on-site. A cost-benefit analysis was then used to study the viability of commercializing the project. The analysis included net present value, internal rate of return and investment payback period. These results showed that the straw pyrolysis project has little risk, and will produce remarkable economic benefits.

关键词： mass balance     heat balance     biomass pyrolysis     economic benefit    

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small-scale silica gel-water adsorption system for domestic air conditioning and water heating by the recovery

Y. YU, Q. W. PAN, L. W. WANG

《能源前沿（英文）》 2020年 第14卷 第2期   页码 328-336 doi: 10.1007/s11708-019-0623-1

摘要： A small-scale silica gel-water adsorption system with modular adsorber, which utilizes solar energy to achieve the cogeneration of domestic air conditioning and water heating effect, is proposed and investigated in this paper. A heat recovery process between two adsorbers and a mass recovery process between two evaporators are adopted to improve the overall cooling and heating performance. First, the adsorption system is tested under different modes (different mass recovery, heat recovery, and cogeneration time) to determine the optimal operating conditions. Then, the cogeneration performance of domestic cooling and water heating effect is studied at different heat transfer fluid temperatures. The results show that the optimal time for cogeneration, mass recovery, and heat recovery are 600 s, 40 s, and 40 s, respectively. When the inlet temperature of hot water is around 85°C, the largest cooling power and heating power are 8.25 kW and 21.94 kW, respectively. Under the condition of cooling water temperature of 35°C, the obtained maximum COP , COP , and SCP of the system are 0.59, 1.39, and 184.5 W/kg, respectively.

关键词： silica gel-water     heat and mass recovery     solar energy     domestic cooling and heating    

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Heat, mass, and work exchange networks

Zhiyou CHEN, Jingtao WANG

《化学科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 484-502 doi: 10.1007/s11705-012-1221-5

摘要： Heat (energy), water (mass), and work (pressure) are the most fundamental utilities for operation units in chemical plants. To reduce energy consumption and diminish environment hazards, various integration methods have been developed. The application of heat exchange networks (HENs), mass exchange networks (MENs), water allocation heat exchange networks (WAHENs) and work exchange networks (WENs) have resulted in the significant saving of energy and water. This review presents the main works related to each network. The similarities and differences of these networks are also discussed. Through comparing and discussing these different networks, this review inspires researchers to propose more efficient and convenient methods for the design of existing exchange networks and even new types of networks including multi-objective networks for the system integration in order to enhance the optimization and controllability of processes.

关键词： process system engineering     integration methods     heat exchange network     mass exchange network     work exchange network    

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Recovery of waste heat in cement plants for the capture of CO

Ruifeng DONG, Zaoxiao ZHANG, Hongfang LU, Yunsong YU

《化学科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 104-111 doi: 10.1007/s11705-011-1166-0

摘要： Large amounts of energy are consumed during the manufacturing of cement especially during the calcination process which also emits large amounts of CO . A large part of the energy used in the making of cement is released as waste heat. A process to capture CO by integrating the recovery and utilization of waste heat has been designed. Aspen Plus software was used to calculate the amount of waste heat and the efficiency of energy utilization. The data used in this study was based on a dry process cement plant with a 5-stage preheater and a precalciner with a cement output of 1 Mt/y. According to the calculations: 1) the generating capacity of the waste heat recovery system is 4.9 MW. 2) The overall CO removal rate was as high as 78.5%. 3) The efficiency of energy utilization increased after the cement producing process was retrofitted with this integrated design.

关键词： cement industry     waste heat     recovery     utilization     CO2 removal    

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Heat and mass transfer of ammonia-water in falling film evaporator

Xianbiao BU, Weibin MA, Huashan LI

《能源前沿（英文）》 2011年 第5卷 第4期   页码 358-366 doi: 10.1007/s11708-011-0161-y

摘要： To investigate the performance of heat and mass transfer of ammonia-water during the process of falling film evaporation in vertical tube evaporator, a mathematical model of evaporation process was presented, the solution of which that needed a coordinate transformation was based on stream function. The computational results from the mathematical model were validated with experimental data. Subsequently, a series of parameters, such as velocity, film thickness and concentration, etc., were obtained from the mathematical model. Calculated results show that the average velocity and the film thickness change dramatically at the entrance region when <100 mm, while they vary slightly with the tube length in the fully developed region when >100 mm. The average concentration of the solution reduces along the tube length because of evaporation, but the reducing tendency becomes slow. It can be concluded that there is an optimalβrelationship between the tube length and the electricity generated. The reason for the bigger concentration gradient in the direction is that the smooth tube is chosen in the calculation. It is suggested that the roll-worked enhanced tube or other enhanced tube can reduce the concentration gradient in the film thickness direction and enhance the heat and mass transfer rate.

关键词： falling film evaporation     ammonia-water     heat and mass transfer    

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A performance analysis of integrated solid oxide fuel cell and heat recovery steam generator for IGFC

Souman RUDRA, H. T. KIM, Jinwook LEE, L. ROSENDAHL,

《能源前沿（英文）》 2010年 第4卷 第3期   页码 402-413 doi: 10.1007/s11708-010-0122-x

摘要： Solid oxide fuel cell (SOFC) is a promising technology for electricity generation. Sulfur-free syngas from a gas-cleaning unit serves as fuel for SOFC in integrated gasification fuel cell (IGFC) power plants. It converts the chemical energy of fuel gas directly into electric energy, thus high efficiencies can be achieved. The outputs from SOFC can be utilized by heat recovery steam generator (HRSG), which drives the steam turbine for electricity production. The SOFC stack model was developed using the process flow sheet simulator Aspen Plus, which is of the equilibrium type. Various ranges of syngas properties gathered from different literature were used for the simulation. The results indicate a trade-off efficiency and power with respect to a variety of SOFC inputs. The HRSG located after SOFC was included in the current simulation study with various operating parameters. This paper describes IGFC power plants, particularly the optimization of HRSG to improve the efficiency of the heat recovery from the SOFC exhaust gas and to maximize the power production in the steam cycle in the IGFC system. HRSG output from different pressure levels varies depending on the SOFC output. The steam turbine efficiency was calculated for measuring the total power plant output. The aim of this paper is to provide a simulation model for the optimal selection of the operative parameters of HRSG and SOFC for the IGFC system by comparing it with other models. The simulation model should be flexible enough for use in future development and capable of predicting system performance under various operating conditions.

关键词： SOFC     HRSG     IGFC     syngas    

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Automated retrofit targeting of heat exchanger networks

Timothy G. Walmsley, Nathan S. Lal, Petar S. Varbanov, Jiří J. Klemeš

《化学科学与工程前沿（英文）》 2018年 第12卷 第4期   页码 630-642 doi: 10.1007/s11705-018-1747-2

摘要：

The aim of this paper is to develop a novel heat exchanger network (HEN) retrofit method based on a new automated retrofit targeting (ART) algorithm. ART uses the heat surplus-deficit table (HSDT) in combination with the Bridge Retrofit concepts to generate retrofit bridges option, from which a retrofit design may be formulated. The HSDT is a tabular tool that shows potential for improved re-integration of heat source and sink streams within a HEN. Using the HSDT, retrofit bridges—a set of modifications that links a cooler to a heater to save energy—may be identified, quantified, and compared. The novel retrofit method including the ART algorithm has been successfully implemented in Microsoft ExcelTM to enable analysis of large-scale HENs. A refinery case study with 27 streams and 46 existing heat exchangers demonstrated the retrofit method’s potential. For the case study, the ART algorithm found 68903 feasible unique retrofit opportunities with a minimum 400 kW·unit−1 threshold for heat recovery divided by the number of new units. The most promising retrofit project required 3 new heat exchanger units to achieve a heat savings of 4.24 MW with a favorable annualised profit and a reasonable payback period.

关键词： process retrofit     pinch analysis     heat exchanger network     heat recovery    

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Exergy analysis of R1234ze(Z) as high temperature heat pump working fluid with multi-stage compression

Bin HU, Di WU, L.W. WANG, R.Z. WANG

《能源前沿（英文）》 2017年 第11卷 第4期   页码 493-502 doi: 10.1007/s11708-017-0510-6

摘要： In this paper, the simulation approach and exergy analysis of multi-stage compression high temperature heat pump (HTHP) systems with R1234ze(Z) working fluid are conducted. Both the single-stage and multi-stage compression cycles are analyzed to compare the system performance with 120°C pressurized hot water supply based upon waste heat recovery. The exergy destruction ratios of each component for different stage compression systems are compared. The results show that the exergy loss ratios of the compressor are bigger than that of the evaporator and the condenser for the single-stage compression system. The multi-stage compression system has better energy and exergy efficiencies with the increase of compression stage number. Compared with the single-stage compression system, the coefficient of performance (COP) improvements of the two-stage and three-stage compression system are 9.1% and 14.6%, respectively. When the waste heat source temperature is 60°C, the exergy efficiencies increase about 6.9% and 11.8% for the two-stage and three-stage compression system respectively.

关键词： multi-stage compression     high temperature heat pump     heat recovery     exergy destruction     R1234ze(Z) working fluid    

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Analysis of a 1 kW organic Rankine cycle using a scroll expander for engine coolant and exhaust heatrecovery

Yiji LU, Anthony Paul ROSKILLY, Long JIANG, Longfei CHEN, Xiaoli YU

《能源前沿（英文）》 2017年 第11卷 第4期   页码 527-534 doi: 10.1007/s11708-017-0516-0

摘要： The development of engine waste heat recovery technologies attracts ever increasing interests due to the rising strict policy requirements and environmental concerns. This paper presented the study of engine coolant and exhaust heat recovery using organic Rankine cycle (ORC). Eight working fluids were selected to evaluate and compare the performance of the integrated waste heat recovery system. Rather than the conventional engine ORC system mainly focusing on the utilization of exhaust energy, this work proposed to fully use the engine coolant energy by changing the designed parameters of the ORC system. The case study selected a small engine as the heat source to drive the ORC system using a scroll expander for power production. The evaluation results suggest that under the engine rated condition, the solution to fully recover the engine coolant energy can achieve a higher power generation performance than that of the conventional engine ORC system. The results suggest that adding a recuperator to the ORC system can potentially improve the system performance when the working fluids are dry and the overall dumped heat demand of the system can be reduced by 12% under optimal conditions. When the ORC evaporating and condensing temperature are respectively set at 85°C and 30°C, the integrated engine waste heat recovery system can improve the overall system efficiency by 9.3% with R600, R600a or -Pentane as the working fluid.

关键词： organic Rankine cycle     scroll expander     coolant and exhaust recovery     internal combustion engine    

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Experimental investigations of frost release by hydrophilic surfaces

Zhongliang LIU, Lingyan HUANG, Yujun GOU, Yaomin LIU

《能源前沿（英文）》 2010年 第4卷 第4期   页码 475-487 doi: 10.1007/s11708-010-0114-x

摘要： Frost formation occurs when water vapor in the surrounding air comes into contact with cold surfaces through heat and mass transfer. It is usually an undesirable phenomenon in most refrigeration and cryogenic systems. A few studies have shown that changing the surface energy, such as increasing the surface hydrophilicity or hydrophobicity, has significant effects on frost growth. In this paper, a kind of hydrophilic polymer paint is formulated to counteract frost deposition on cold surfaces. The coated surface can retard frost formation up to three hours under low plate temperatures (-15.3°C) and high air humidity (72%). To test the antifrosting performance of the hydrophilic paint under more practical conditions, it is applied to a fin-and-tube heat exchanger and a domestic refrigerator at a coating thickness of 30 μm. Comparisons of frost deposition, pressure drops, and outlet temperatures are made between uncoated and coated heat exchangers. Under conditions of high air temperature (2.2°C) and relative high air humidity (90%), the paint prolongs the defrosting interval from 80 to 137 min. Experimental observations also show that the coated hydrophilic fins are free of frost deposition during the entire course of the test and that the coating has no significant additional thermal resistance.

关键词： frost formation     hydrophilicity     heat and mass transfer     performance    

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A review on membrane distillation in process engineering: design and exergy equations, materials and wetting problems

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 592-613 doi: 10.1007/s11705-021-2105-3

摘要： One of the problems that most afflicts humanity is the lack of clean water. Water stress, which is the pressure on the quantity and quality of water resources, exists in many places throughout the World. Desalination represents a valid solution to the scarcity of fresh water and several technologies are already well applied and successful (such as reverse osmosis), producing about 100 million m3·d−1 of fresh water. Further advances in the field of desalination can be provided by innovative processes such as membrane distillation. The latter is of particular interest for the treatment of waste currents from conventional desalination processes (for example the retentate of reverse osmosis) as it allows to desalt highly concentrated currents as it is not limited by concentration polarization phenomena. New perspectives have enhanced research activities and allowed a deeper understanding of mass and heat transport phenomena, membrane wetting, polarization phenomena and have encouraged the use of materials particularly suitable for membrane distillation applications. This work summarizes recent developments in the field of membrane distillation, studies for module length optimization, commercial membrane modules developed, recent patents and advancement of membrane material.

关键词： membrane distillation     recent developments     heat and mass transfer     wetting     membrane material    

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Acceleration of the particulate organic matter hydrolysis by start-up stage recovery and its original

Yanqing Duan, Aijuan Zhou, Xiuping Yue, Zhichun Zhang, Yanjuan Gao, Yanhong Luo, Xiao Zhang

《环境科学与工程前沿（英文）》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1304-3

摘要： Abstract • Carbon availability was partially solved by POM recovery and fermentation. • 12% carbon sources were regenerated by fermentation of the entrapped 35% TCOD. • The unique microbial communities facilitated the efficient hydrolysis of the POM. • Considerable economic benefits in aeration power and ECS dosage were anticipated. To address the availability of carbon sources for denitrification, the accelerated hydrolysis of the most abundant but low-availability fraction of particulate organic matter (POM) was investigated. Mesh sieves with different pore sizes were used as primary pretreatment at the start-up-stage of the biological process to separate some POM from the liquid system. The changes in soluble carbohydrates and proteins were monitored to investigate the hydrolysis performance of the sieved POM, with waste activated sludge (WAS) as the control test. The results showed that an average of 35% POM could be entrapped before filtrate mat development. In addition, benefiting from the high polysaccharides concentration, as well as the high availability due to the relatively loose physical structure, a 23% hydrolysis efficiency of POM was obtained, in contrast to that of WAS (3.4%), with a hydrolysis constant of 0.39 h−1. The prominent performance was also attributed to the unique microbial communities having been domesticated at a lower temperature, especially the cellulose-degrading bacteria Paraclostridium and psychrophile Psychrobacter, making up 6.94% and 2.56%, respectively. Furthermore, the potential benefits and application of improved POM hydrolysis by start-up stage recovery via mesh sieves combined with anaerobic fermentation were evaluated, including selective POM entrapment, alleviation of blockage and wear, and a reduction in aeration energy. By the proposed strategy, carbon availability for biological nutrient removal (BNR) processes is anticipated to be improved more economically than that can be achieved by primary clarifier elimination.

关键词： Particulate organic matter (POM)     Hydrolysis     Microbial community     Mass balance    

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Research progress in liquid desiccant air-conditioning devices and systems

Xiaohua LIU, Yi JIANG, Shuanqiang LIU, Xiaoyang CHEN,

《能源前沿（英文）》 2010年 第4卷 第1期   页码 55-65 doi: 10.1007/s11708-009-0082-1

摘要： The developments on liquid desiccant air-conditioning systems were illustrated and summarized in this paper. In order to obtain a better dehumidification (or humidification) performance, liquid desiccant should be cooled (or heated) rather than air. Two fundamental modules were proposed, including basic spray module with extra heat exchanger and total heat recovery device, which could be combined to set up various kinds of liquid desiccant air processors. The operating principle of heat pump-driven outdoor air processor as well as heat-driven outdoor air processor was analyzed. The COP of the heat pump (or power)-driven outdoor air processor could be as high as 5.0 both in summer and in winter operating conditions. The COP of the hot water-driven processor (65°C–80°C) was 1.19 and 0.93, respectively, using evaporative indoor exhaust air or cooling water to cool the dehumidification process. The liquid desiccant air processor-based temperature and humidity-independent control air-conditioning system could save 20%–30% operating energy compared with the conventional air-conditioning system.

关键词： liquid desiccant     heat and mass transfer     performance     air-conditioning    

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Energy-efficient recovery of tetrahydrofuran and ethyl acetate by triple-column extractive distillation

Ao Yang, Yang Su, Tao Shi, Jingzheng Ren, Weifeng Shen, Teng Zhou

《化学科学与工程前沿（英文）》 2022年 第16卷 第2期   页码 303-315 doi: 10.1007/s11705-021-2044-z

摘要： An energy-efficient triple-column extractive distillation process is developed for recovering tetrahydrofuran and ethyl acetate from industrial effluent. The process development follows a rigorous hierarchical design procedure that involves entrainer design, thermodynamic analysis, process design and optimization, and heat integration. The computer-aided molecular design method is firstly used to find promising entrainer candidates and the best one is determined via rigorous thermodynamic analysis. Subsequently, the direct and indirect triple-column extractive distillation processes are proposed in the conceptual design step. These two extractive distillation processes are then optimized by employing an improved genetic algorithm. Finally, heat integration is performed to further reduce the process energy consumption. The results indicate that the indirect extractive distillation process with heat integration shows the highest performance in terms of the process economics.

关键词： extractive distillation     solvent selection     conceptual design     process optimization     heat integration    

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Typical off-design analytical performances of internal combustion engine cogeneration

Xiaohong HE, Ruixian CAI

《能源前沿（英文）》 2009年 第3卷 第2期   页码 184-192 doi: 10.1007/s11708-009-0007-z

摘要： Based on experimental data, typical off-design characteristic curves with corresponding formulas of internal combustion engine (ICE) are summarized and investigated. In combination with analytical solution of single-pressure heat recovery steam generator (HRSG) and influence of ambient pressure on combined heat and power (CHP) system, off-design operation regularities of ICE cogeneration are analyzed. The approach temperature difference Δ , relative steam production and superheated steam temperature decrease with the decrease in engine load. The total energy efficiency, equivalent exergy efficiency and economic exergy efficiency first increase and then decrease. Therefore, there exists an optimum value, corresponding to ICE best efficiency operating condition. It is worth emphasizing that Δ is likely to be negative in low load condition with high design steam parameter and low ICE design exhaust gas temperature. Compared with single shaft gas turbine cogeneration, Δ in ICE cogeneration is more likely to be negative. The main reason for this is that the gas turbine has an increased exhaust gas flow with the decrease in load; while ICE is on the contrary. Moreover, ICE power output and efficiency decrease with the decrease in ambient pressure. Hence, approach temperature difference, relative steam production and superheated steam temperature decrease rapidly while the cogeneration efficiencies decrease slightly. It is necessary to consider the influence of ambient conditions, especially the optimization of ICE performances at different places, on cogeneration performances.

关键词： internal combustion engine (ICE)     cogeneration     heat recovery steam generator (HRSG)     off-design     superheated steam     saturated steam     ambient pressure    

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标题 作者 时间 类型 操作

Mass and heat balance calculations and economic evaluation of an innovative biomass pyrolysis project

Quanyuan WEI, Yongshui QU, Tianwei TAN

期刊论文

small-scale silica gel-water adsorption system for domestic air conditioning and water heating by the recovery

Y. YU, Q. W. PAN, L. W. WANG

期刊论文

Heat, mass, and work exchange networks

Zhiyou CHEN, Jingtao WANG

期刊论文

Recovery of waste heat in cement plants for the capture of CO

Ruifeng DONG, Zaoxiao ZHANG, Hongfang LU, Yunsong YU

期刊论文

Heat and mass transfer of ammonia-water in falling film evaporator

Xianbiao BU, Weibin MA, Huashan LI

期刊论文

A performance analysis of integrated solid oxide fuel cell and heat recovery steam generator for IGFC

Souman RUDRA, H. T. KIM, Jinwook LEE, L. ROSENDAHL,

期刊论文

Automated retrofit targeting of heat exchanger networks

Timothy G. Walmsley, Nathan S. Lal, Petar S. Varbanov, Jiří J. Klemeš

期刊论文

Exergy analysis of R1234ze(Z) as high temperature heat pump working fluid with multi-stage compression

Bin HU, Di WU, L.W. WANG, R.Z. WANG

期刊论文

Analysis of a 1 kW organic Rankine cycle using a scroll expander for engine coolant and exhaust heatrecovery

Yiji LU, Anthony Paul ROSKILLY, Long JIANG, Longfei CHEN, Xiaoli YU

期刊论文

Experimental investigations of frost release by hydrophilic surfaces

Zhongliang LIU, Lingyan HUANG, Yujun GOU, Yaomin LIU

期刊论文

A review on membrane distillation in process engineering: design and exergy equations, materials and wetting problems

期刊论文

Acceleration of the particulate organic matter hydrolysis by start-up stage recovery and its original

Yanqing Duan, Aijuan Zhou, Xiuping Yue, Zhichun Zhang, Yanjuan Gao, Yanhong Luo, Xiao Zhang

期刊论文

Research progress in liquid desiccant air-conditioning devices and systems

Xiaohua LIU, Yi JIANG, Shuanqiang LIU, Xiaoyang CHEN,

期刊论文

Energy-efficient recovery of tetrahydrofuran and ethyl acetate by triple-column extractive distillation

Ao Yang, Yang Su, Tao Shi, Jingzheng Ren, Weifeng Shen, Teng Zhou

期刊论文

Typical off-design analytical performances of internal combustion engine cogeneration

Xiaohong HE, Ruixian CAI

期刊论文